Captain Mack has appeared in every episode of the series. His appearances in full are listed below:
- CM Scary Spider
- CM Shall We Dance?
- CM Super Dooper Litter Scooper
- CM Mouse Hunt
- CM The Mayor's Birthday
- CM Catch It If You Can
- CM Super Galactic Amazer Gazer
- CM Tender Tulip
- CM Fairy Story
- CM What's Up Pussycat?
- CM Mighty Muffin Maker
- CM Pirate Pinkbeard
- CM Call Captain Mack
- CM Princess Fussy Pants
- CM Hatching A Plan
- CM Ghost!
- CM Football Frenzy
- CM Picture Perfect
- CM Sunshine City Band
- CM Sing Maximus Sing
- CM Which Witch
- CM Sunshine City Goldrush
- CM Tour de Sunshine
- CM Baby Oscar
- CM Mood Machine
- CM Happy Holiday
- CM Good Sport
- CM A Pumpkin Problem
- CM Fast Forward
- CM Everyone's A Winner
- CM Green Fingered Grabby
- CM Just Desserts
- CM Fireman Grabby
- CM Camping Catastrophe
- CM Arty Marty
- CM A Very Meddly Xmas
- CM Absurd Bird
- CM Purple Fly
- CM Snakes In The City
- CM Magic Vase
- CM Going Going Gone
- CM Happy Feet
- CM In A Fix
- CM Gigglepuff
- CM Hyper Healthy
- CM Gold Meddling
- CM Happy Birthday Camilla
- CM Easter Egg Hunt
- CM Weather Machine
- CM Lucky Unlucky
- CM The Big Orange Grab
- CM Blooming Marvellous
- WB Captain Mack and the Giant Squid
- WB Captain Mack and the Monstrous Moon Mites
- WB Captain Mack and the Slithery Serpent
- WB Captain Mack and the Abominable Snow Monster
